全文获取类型
收费全文 | 1454篇 |
免费 | 56篇 |
国内免费 | 18篇 |
专业分类
化学 | 1020篇 |
晶体学 | 12篇 |
力学 | 63篇 |
数学 | 162篇 |
物理学 | 271篇 |
出版年
2024年 | 4篇 |
2023年 | 21篇 |
2022年 | 20篇 |
2021年 | 61篇 |
2020年 | 66篇 |
2019年 | 68篇 |
2018年 | 76篇 |
2017年 | 39篇 |
2016年 | 62篇 |
2015年 | 50篇 |
2014年 | 83篇 |
2013年 | 166篇 |
2012年 | 129篇 |
2011年 | 104篇 |
2010年 | 75篇 |
2009年 | 61篇 |
2008年 | 51篇 |
2007年 | 44篇 |
2006年 | 55篇 |
2005年 | 27篇 |
2004年 | 32篇 |
2003年 | 17篇 |
2002年 | 17篇 |
2001年 | 19篇 |
2000年 | 23篇 |
1999年 | 12篇 |
1998年 | 6篇 |
1997年 | 9篇 |
1996年 | 5篇 |
1995年 | 9篇 |
1994年 | 12篇 |
1992年 | 4篇 |
1990年 | 3篇 |
1989年 | 3篇 |
1987年 | 9篇 |
1986年 | 4篇 |
1985年 | 5篇 |
1984年 | 5篇 |
1983年 | 7篇 |
1982年 | 5篇 |
1981年 | 4篇 |
1979年 | 6篇 |
1978年 | 8篇 |
1977年 | 3篇 |
1976年 | 6篇 |
1974年 | 7篇 |
1966年 | 2篇 |
1960年 | 5篇 |
1959年 | 3篇 |
1958年 | 2篇 |
排序方式: 共有1528条查询结果,搜索用时 468 毫秒
61.
62.
Fadhel Al‐Musallam Amin Boumenir 《Mathematical Methods in the Applied Sciences》2014,37(11):1610-1623
We are concerned with the reconstruction of a non‐differentiable acoustic stiffness reactance coefficient of a one‐dimensional hyperbolic equation using the smallest possible number of boundary readings generated by classical initial conditions. To this end, a complete set of spectral data of a string is extracted from either a single or at most two readings of the trace of the solution on the boundary. The sought coefficient is then uniquely recovered by the Krein inverse spectral theory. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
63.
Basma H. Amin Mohamed I. Abou-Dobara Mostafa A. Diab Essam A. Gomaa Mohammed A. El-Mogazy Adel Z. El-Sonbati Mohamed S. EL-Ghareib Mostafa A. Hussien Hanaa M. Salama 《应用有机金属化学》2020,34(8):e5689
A novel series of mixed-ligand complexes of 5,5′-{(1E,1E′)-1,4-phenelynebis(diazene-2,1-diyl)}bis(quinolin-8-ol) (H2L1) as a primary ligand and 4-aminoantipyrine(L2) as a secondary ligand with Mn(II) ion were prepared using two general formulae: [Mn2(H2L1)2(L2)2X4].4Cl (X = OH2( 1 ), ONO2−( 2 ), Cl=nil; OAc( 3 ), Cl = nil) and [Mn2(H2L1)(L2)2(O2SO2)2]( 4 ). Free ligands and their complexes were characterized. Electronic absorption spectra of the mixed-ligand complexes indicate a distorted octahedral geometry around the central metal ion, and the anions X− are in the axial positions for all compounds. The ligands behave in a neutral bidentate manner, through nitrogen atoms and oxygen atoms of the carbonyl group (L2), whereas H2L1 coordinated through nitrogen and OH groups as a neutral bidentate ligand. All complexes do not contain coordinated water molecules, but complex ( 1 ) contains four water molecules. The water molecules are removed in a single step. The complexes exhibited magnetic susceptibility corresponding to five unpaired electrons. The antimicrobial activity of the Mn(II) mixed-ligand complexes ( 1–4 ) against two gram-positive bacteria, three local gram-negative bacteria, and three fungi species was tested. Mn(II) mixed-ligand complex ( 2 ) exhibited significant antibacterial activity against Bacillus cereus, Staphylococcus aureus, Escherichia coli, Klebsiella pneumoniae, and Pseudomonas sp. Mixed-ligand complex ( 2 ) exhibited a high potential cytotoxicity against the growth of human lung cancer cells. 相似文献
64.
Naghmeh Esfandiary Farzane Pazoki Athar Nakisa Kobra Azizi Iman Radfar Akbar Heydari 《应用有机金属化学》2020,34(8):e5725
A highly efficient Fe3O4@VitB1–Ag(I) magnetic catalyst has been obtained using surface modification of Fe3O4. To this end, silver chloride was immobilized on Fe3O4 nanoparticles via vitamin B1 biomolecules. The synthesized biocompatible magnetic catalyst was applied in an A3-coupling reaction in the presence of aldehyde, amine and phenyl acetylene under solvent-free conditions and afforded the desired products in excellent yields. Also, interactions between metal and ligand in the Fe3O4@VitB1–Ag(I) were studied using theoretical calculations. 相似文献
65.
66.
Mohammad Ali Zolfigol Ardeshir Khazaei Arash Ghorbani-Choghamarani Amin Rostami 《Phosphorus, sulfur, and silicon and the related elements》2013,188(11):2453-2458
The regeneration of carbonyl compounds from oximes were performed by using silica chromate and wet SiO 2 (w/w 50%) under microwave irradiation and solvent-free conditions with excellent yields. 相似文献
67.
68.
69.
70.
This article provides a critical review of the different applications of ferrocene‐based peptides/amides in biological as well as in non‐biological systems. Ferrocene‐based peptides/amides find many applications in different fields such as materials science, medicine, organic synthesis, bio‐organometallic and biological chemistry, asymmetric catalysis, nonlinear optics, in polymer science as redox active polymers and dendrimers, in molecular recognition as biosensors and in electrochemistry). Extensive research is being done on ferrocene‐based peptides/amides but we will highlight the various applications of ferrocene‐based peptides/amides for the period 2006–2010. The main factors that govern the potential biological and non‐biological applications are an electroactive core, a conjugated linker that can act as a chromophore and lower the oxidation potential of the ferrocene part, an amino acid or peptide derivative that can interact with other molecules via hydrogen bonding or any secondary bonding, and symmetric and asymmetric substitution on the ferrocene moiety. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献